Methyl oleate

Names

[ CAS No. ]:
112-62-9

[ Name ]:
Methyl oleate

[Synonym ]:
Kemester 115
Kemester 104
methyl cis-9-octadecenoate
Kemester 105
Emery 2219
Methyl cis-9-octadecenoate C18:1
Methyl cis-9-octadecenoate,Oleic acid methyl ester
emerest2801
methyl 9-octadecenoate
Esterol 112
Methyl Oleate
Methyloleat
(Z)-9-Octadecenoic acid methyl ester
Emerest 2301
EINECS 203-992-5
Oleic Acid Methyl Ester
Emery 2301
MFCD00009578

Biological Activity

[Description]:

Methyl oleate is a fatty acid methyl ester (FAME). Methyl oleate substantially improves the antioxidation ability but markedly impaired the antiwear capacity of zinc dialkyldithiophosphate (ZDDP)[1].

[Related Catalog]:

Research Areas >> Others

Signaling Pathways >> Others >> Others

[References]

[1]. Wang J, et al. Engine Oil Degradation Induced by Biodiesel: Effect of Methyl Oleate on the Performance of Zinc Dialkyldithiophosphate.ACS Omega. 2019 Sep 18;4(14):16166-16170.

Chemical & Physical Properties

[ Density]:
0.9±0.1 g/cm3

[ Boiling Point ]:
351.4±0.0 °C at 760 mmHg

[ Melting Point ]:
-20 °C

[ Molecular Formula ]:
C₁₉H₃₆O₂

[ Molecular Weight ]:
296.488

[ Flash Point ]:
92.4±20.4 °C

[ Exact Mass ]:
296.271515

[ PSA ]:
26.30000

[ LogP ]:
8.16

[ Vapour Pressure ]:
0.0±0.7 mmHg at 25°C

[ Index of Refraction ]:
1.454

[ Storage condition ]:
−20°C

[ Stability ]:
Stable, but air and light sensitive. Incompatible with strong oxidizing agents. Combustible.

MSDS

Click to get detail MSDS

Toxicological Information

CHEMICAL IDENTIFICATION

RTECS NUMBER :: RK0895000

CHEMICAL NAME :: Oleic acid, methyl ester, cis-

CAS REGISTRY NUMBER :: 112-62-9

LAST UPDATED :: 199706

DATA ITEMS CITED :: 7

MOLECULAR FORMULA :: C19-H36-O2

MOLECULAR WEIGHT :: 296.55

WISWESSER LINE NOTATION :: 9U8VO1 -C

HEALTH HAZARD DATA

ACUTE TOXICITY DATA

TYPE OF TEST :: TDLo - Lowest published toxic dose

ROUTE OF EXPOSURE :: Administration onto the skin

SPECIES OBSERVED :: Rodent - mouse

DOSE/DURATION :: 54 gm/kg/45W-I

TOXIC EFFECTS :: Tumorigenic - equivocal tumorigenic agent by RTECS criteria Blood - leukemia Skin and Appendages - tumors

REFERENCE :: AMBPBZ Acta Pathologica et Microbiologica Scandinavica, Section A: Pathology. (Copenhagen, Denmark) V.78-89, 1970-81. For publisher information, see ACPADQ. Volume(issue)/page/year: 82,127,1974 *** OCCUPATIONAL EXPOSURE LIMITS *** OEL-AUSTRALIA:STEL 10 ppm JAN 1993 OEL-BELGIUM:STEL 10 ppm JAN 1993 OEL-UNITED KINGDOM:TWA 5 mg/m3 (resp. dust) JAN 1993 *** NIOSH STANDARDS DEVELOPMENT AND SURVEILLANCE DATA *** NIOSH OCCUPATIONAL EXPOSURE SURVEY DATA : NOHS - National Occupational Hazard Survey (1974) NOHS Hazard Code - 83646 No. of Facilities: 2265 (estimated) No. of Industries: 45 No. of Occupations: 43 No. of Employees: 31786 (estimated) NOES - National Occupational Exposure Survey (1983) NOES Hazard Code - 83646 No. of Facilities: 3726 (estimated) No. of Industries: 43 No. of Occupations: 40 No. of Employees: 36455 (estimated) No. of Female Employees: 1254 (estimated)

Safety Information

[ Symbol ]:

GHS02, GHS07, GHS08, GHS09

[ Signal Word ]:
Danger

[ Hazard Statements ]:
H225-H304-H315-H336-H410

[ Precautionary Statements ]:
P210-P261-P273-P301 + P310-P331-P501

[ Personal Protective Equipment ]:
Eyeshields;Gloves;half-mask respirator (US);multi-purpose combination respirator cartridge (US)

[ Hazard Codes ]:
F,Xn,N

[ Risk Phrases ]:
R11

[ Safety Phrases ]:
S23-S24/25-S62-S61-S60-S33-S29-S16-S9

[ RIDADR ]:
UN 1206 3/PG 2

[ WGK Germany ]:
1

[ RTECS ]:
RK0895000

[ HS Code ]:
29161500

Synthetic Route

Click to get detail synthetic route

Precursor & DownStream

Precursor

DownStream

Customs

[ HS Code ]: 2916190090

[ Summary ]:
2916190090 unsaturated acyclic monocarboxylic acids, their anhydrides, halides, peroxides, peroxyacids and their derivatives。supervision conditions:AB(certificate of inspection for goods inward,certificate of inspection for goods outward)。VAT:17.0%。tax rebate rate:9.0%。MFN tariff:6.5%。general tariff:30.0%

Articles

Optimization of supercritical fluid consecutive extractions of fatty acids and polyphenols from Vitis vinifera grape wastes.

J. Food Sci. 80(1) , E101-7, (2015)

In this study, supercritical fluid extraction has been successfully applied to a sequential fractionation of fatty acids and polyphenols from wine wastes (2 different vitis vinifera grapes). To this a...

Effect of different biosynthetic precursors on the production of nargenicin A1 from metabolically engineered Nocardia sp. CS682.

J. Microbiol. Biotechnol. 22(8) , 1127-32, (2012)

Nargenicin A1 is a 28-membered polyketide macrolide, with antibacterial activity against methicillin-resistant Staphylococcus aureus, produced by Nocardia sp. CS682. In this study, the production of n...

Ultrasound intensification suppresses the need of methanol excess during the biodiesel production with Lipozyme TL-IM.

Ultrason. Sonochem. 27 , 530-5, (2015)

The synthesis of biodiesel from sunflower oil and methanol based on transesterification using the immobilized lipase from Thermomyces lanuginosus (Lipozyme TL-IM) has been investigated under silent co...