Electrochemical desulfurization of (1-adamantyl)(alkylsulfonyl) pyridines

LM Korotaeva, TY Rubinskaya, IA Rybakova…

Index: Korotaeva; Rubinskaya; Rybakova; Gultyai Russian Chemical Bulletin, 2008 , vol. 57, # 1 p. 90 - 94

Full Text: HTML

Citation Number: 2

Abstract

Abstract The electroreduction of 4-(1-adamantyl)-2-(alkylsulfonyl) pyridines and 2-(1- adamantyl)-4-(tert-butylsulfonyl) pyridine was studied by polarography and preparative electrolysis on the mercury cathode at various compositions of the supporting electrolyte. Under the preparative electrolysis conditions, the C Py-S bond is predominantly cleaved to form the corresponding adamantylpyridines. The conditions for selective electrochemical ...

Related Articles:

The functionalization of saturated hydrocarbons. Part 26. Ionic substitution reactions in GoAgg IV chemistry: The construction of C N, C S and C C bonds

[Barton, Derek H. R.; Warinthorn, Chavasiri Tetrahedron, 1994 , vol. 50, # 1 p. 47 - 60]

Functionalisation of saturated hydrocarbons. part x. 1 a comparative study of chemical and electrochemical processes (gif and gif-orsay systems) in pyridine in …

[Belavoine, Gilbert; Barton, Derek H. R.; Boivin, Jean; Gref, Aurore; Coupanec, Pascale Le; et al. Tetrahedron, 1988 , vol. 44, # 4 p. 1091 - 1106]

More Articles...