Catalytic alkyl group exchange reaction of primary and secondary amines
S Murahashi, N Yoshimura, T Tsumiyama…
Index: Murahashi; Yoshimura; Tsumiyama; Kojima Journal of the American Chemical Society, 1983 , vol. 105, # 15 p. 5002 - 5011
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Citation Number: 162
Abstract
Conclusion Proton-transfer rates between B and HA depend on the B/H/A angle and the B/HA distance. Ideally one would like to construct a three-dimensional map having reactivity, angularity, and distance as its axes. Each point on the map would represent a rate constant from a rigid molecule in which B and HA are fixed in a particular ground-state geometry. We have synthesized three such systems, and the data on them are easily summarized: The ...
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