Reactions of benzoyl (carbonyl) transition metal complexes with LiNMe2: on the feasibility of a reaction route to α-keto amide through an acyl (carbamoyl) cobalt …

…, K Masuzoe, F Ozawa, A Yamamoto

Index: Kawasaki, Nobuo; Masuzoe, Kenji; Ozawa, Fumiyuki; Yamamoto, Akio Journal of Organometallic Chemistry, 1989 , vol. 361, p. C37 - C40

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Abstract

Abstract CO-coordinated benzoyltransition metal complexes, PhCOCo (CO) 3 L (L PPh 3, PCy 3, and PMe 3), PhCOMn (CO) 5, have been prepared and their reactions with LiNMe 2 examined. The reactions give α-keto amide (PhCO-CONMe 2) after treating the systems with Br 2 or organic halides.

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