Palladium-catalyzed double carbonylation of aryl halides to give. alpha.-keto amides. Mechanistic studies
…, H Soyama, H Yanagihara, I Aoyama…
Index: Ozawa, Fumiyuki; Soyama, Hidehiko; Yanagihara, Hisayoshi; Aoyama, Issei; Takino, Hiroaki; et al. Journal of the American Chemical Society, 1985 , vol. 107, # 11 p. 3235 - 3245
Full Text: HTML
Citation Number: 170
Abstract
Abstract: Various aryl halides are catalytically converted into a-keto amides and amides on treatment with secondary amines and carbon monoxide. Palladium complexes containing tertiary phosphine ligands, particularly diphenylmethylphosphine and 1, 4-bis (diphenylphosphino) butane, are most effective among other transition-metal complexes. Detailed examination of factors controlling the reaction rates and selectivity for a-keto ...
Related Articles:
[Mueller, Paul; Godoy, Jose Tetrahedron Letters, 1982 , vol. 23, # 36 p. 3661 - 3664]
[Kawasaki, Nobuo; Masuzoe, Kenji; Ozawa, Fumiyuki; Yamamoto, Akio Journal of Organometallic Chemistry, 1989 , vol. 361, p. C37 - C40]
[Zhang, Xiaobin; Yang, Wenchao; Wang, Lei Organic and Biomolecular Chemistry, 2013 , vol. 11, # 22 p. 3649 - 3654]
[Kolasa, Teodozyj; Miller, Marvin J. Journal of Organic Chemistry, 1987 , vol. 52, # 22 p. 4978 - 4984]
[Kolasa, Teodozyj; Miller, Marvin J. Journal of Organic Chemistry, 1987 , vol. 52, # 22 p. 4978 - 4984]