Heterocycles

Regiocontrol in Pd-catalyzed allylic substitution with P, N-ligand

K Kondo, K Kazuta, A Saitoh, Y Murakami

Index: Kondo, Kazuhiro; Kazuta, Kumiko; Saitoh, Atsushi; Murakami, Yasuoki Heterocycles, 2003 , vol. 59, # 1 p. 97 - 100

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Citation Number: 8

Abstract

Résumé/Abstract A racemic ligand,(′)-N-[2-(diphenylphosphino) naphthyl]-2- (pyrrolidinylmethyl) piperidine, has been found to exhibit better regioselectivity than the racemic Pfaltz ligand, BINAP and dppp in the palladium-catalyzed regioselective allylic substitution with the use of (E)-1-phenyl-4-alkoxy-2-butenyl acetate as the substrate.

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