Electronic effects in solvolysis reactions. III. Solvolysis of allyl-substituted cumyl derivatives

LB Jones, JP Foster

Index: Jones,L.B.; Foster,J.P. Journal of Organic Chemistry, 1970 , vol. 35, p. 1777 - 1781

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Citation Number: 13

Abstract

Thermal Decomposition of a-Hydroperoxytetrahydrofuran (I). A. Pyrolysis in the Gas Chromatograph.-A l-pl sample of a 4.3 X 10-2 M solution of I in THF was injected into a Beckman GC-5 gas chromatograph equipped with a flame ionization de- tector and a 6 ft X 0.125 in. Carbowax column on Chromosorb w. The gas chromatogram showed two major peaks for butyrolac- tone and or-hydroxytetrahydrofuran in a ratio of ca. 1 :3. B. Pyrolysis in a Sealed Tube.-A 5-ml ...