Phosphine containing oligonucleotides for the development of metallodeoxyribozymes.
Loïc Ropartz, Nico J Meeuwenoord, Gijsbert A van der Marel, Piet W N M van Leeuwen, Alexandra M Z Slawin, Paul C J Kamer
Index: Chem. Commun. (Camb.) (15) , 1556-8, (2007)
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Abstract
Novel transition metal catalysts based on oligonucleotides can be easily obtained by functionalization of 5-iodouridine with phosphine ligands, resulting in good asymmetric induction in palladium catalyzed allylic nucleophilic substitution.
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