Alkylation of Carbonyl Compounds in Water: Formation of C C and C O Bonds in the Presence of Surfactants
…, S Cerritelli, M Chiarini, P De Maria…
Index: Cerichelli, Giorgio; Cerritelli, Simona; Chiarini, Marco; De Maria, Paolo; Fontana, Antonella Chemistry - A European Journal, 2002 , vol. 8, # 22 p. 5204 - 5210
Full Text: HTML
Citation Number: 18
Abstract
Abstract The formation of C [BOND] C and C [BOND] O bonds by the reaction of enolate intermediates with electrophilic substrates commonly requires strong bases, aprotic solvents and very low temperatures. A way of performing the same reactions with sodium hydroxide at moderate temperatures in aqueous surfactant solutions is presented. Different halides, ketones and surfactants (cationic, zwitterionic and anionic) have been used. The results ...
Related Articles:
Microwave-assisted solid-liquid phase alkylation of naphthols
[Balint, Erika; Kovacs, Orsolya; Drahos, Laszlo; Keglevich, Gyoergy Letters in Organic Chemistry, 2013 , vol. 10, # 5 p. 330 - 336]
[Maslak, Przemyslaw; Guthrie, Robert D. Journal of the American Chemical Society, 1986 , vol. 108, # 10 p. 2637 - 2640]
Microwave-assisted solid-liquid phase alkylation of naphthols
[Balint, Erika; Kovacs, Orsolya; Drahos, Laszlo; Keglevich, Gyoergy Letters in Organic Chemistry, 2013 , vol. 10, # 5 p. 330 - 336]
[Shintou, Taichi; Mukaiyama, Teruaki Journal of the American Chemical Society, 2004 , vol. 126, # 23 p. 7359 - 7367]
Mechanism of reactions promoted by polymer-supported phase-transfer catalysts
[Montanari, Fernando; Quici, Silvio; Tundo, Pietro Journal of Organic Chemistry, 1983 , vol. 48, # 2 p. 199 - 202]