Electron apportionment in cleavage of radical anions. 2. Naphthylmethyl phenyl ethers vs. naphthyl benzyl ethers
P Maslak, RD Guthrie
Index: Maslak, Przemyslaw; Guthrie, Robert D. Journal of the American Chemical Society, 1986 , vol. 108, # 10 p. 2637 - 2640
Full Text: HTML
Citation Number: 44
Abstract
Abstract: Naphthylmethyl phenyl ethers and naphthyl benzyl ethers were found to undergo scission of the H2C-0 bond when treated with radical anions of anthracene or fluoranthene. Under comparable conditions, ethers of the naphthylmethyl phenyl series (a and 8) reacted more than lo4 times faster than ethers of the naphthyl benzyl series (a and 8). This preference for regioconservation of spin density in the scission process is interpreted in ...
Related Articles:
Microwave-assisted solid-liquid phase alkylation of naphthols
[Balint, Erika; Kovacs, Orsolya; Drahos, Laszlo; Keglevich, Gyoergy Letters in Organic Chemistry, 2013 , vol. 10, # 5 p. 330 - 336]
Microwave-assisted solid-liquid phase alkylation of naphthols
[Balint, Erika; Kovacs, Orsolya; Drahos, Laszlo; Keglevich, Gyoergy Letters in Organic Chemistry, 2013 , vol. 10, # 5 p. 330 - 336]
[Shintou, Taichi; Mukaiyama, Teruaki Journal of the American Chemical Society, 2004 , vol. 126, # 23 p. 7359 - 7367]
Mechanism of reactions promoted by polymer-supported phase-transfer catalysts
[Montanari, Fernando; Quici, Silvio; Tundo, Pietro Journal of Organic Chemistry, 1983 , vol. 48, # 2 p. 199 - 202]
[Cerichelli, Giorgio; Cerritelli, Simona; Chiarini, Marco; De Maria, Paolo; Fontana, Antonella Chemistry - A European Journal, 2002 , vol. 8, # 22 p. 5204 - 5210]