Reactions of 2-Acyl-1, 3-indandiones with Nitrogen Nucleophiles

P Hrnčiar, E Švanygová

Index: Hrnciar, Pavel; Svanygova, Eva Collection of Czechoslovak Chemical Communications, 1994 , vol. 59, # 12 p. 2734 - 2740

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Abstract

Abstract Reactions of 2-acyl-1, 3-indandiones with nitrogen nucleophiles were studied rarely. The question, if they react with carbonyl carbon of acyl group or indandione skeleton, has not been answered unambiguously. To make clear the question which carbonyl carbon of 2-acyl-1, 3-indandiones enters the reaction with nitrogen nucleophiles we carried out the reactions with 2-acetyl-(Ia), 2-propionyl-(Ib), 2-pivaloyl-(Ic), and 2-benzoyl-1, 3-indandione ...