Synlett

Sustainable Suzuki-Miyaura reaction catalyzed by Pd (OAc) 2 immobilized on reversed-phase alumina

H Hagiwara, KH Ko, T Hoshi, T Suzuki

Index: Hagiwara, Hisahiro; Keon, Hyeok Ko; Hoshi, Takashi; Suzuki, Toshio Synlett, 2008 , # 4 p. 611 - 613

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Abstract

Abstract Employing Pd (OAc) 2 immobilized on amorphous N, N-diethylaminopropyl alumina, Suzuki-Miyaura coupling of aryl halide with arylboronic acid was realized in 50% aqueous ethanol at room temperature, which enabled repeated use up to four times in 96% average yield and achieved a turnover number of 15 000.

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