Extended para-hydrogenation monitored by NMR spectroscopy.
Joel A Tang, Francesca Gruppi, Roman Fleysher, Daniel K Sodickson, James W Canary, Alexej Jerschow
Index: Chem. Commun. (Camb.) 47(3) , 958-60, (2011)
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Abstract
A system that provides a sustained hyperpolarized (1)H NMR signal in an aqueous medium is reported. The enhanced signal lasts much longer than typical (1)H T(1) values, uncovering new possibilities for implementing hyperpolarized (1)H NMR/MRI experiments or performing kinetics studies that would not otherwise be detectable.
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