4??(N, N??Dimethylamino) pyridine??Embedded Nanoporous Conjugated Polymer as a Highly Active Heterogeneous Organocatalyst

Y Zhang, Y Zhang, YL Sun, X Du, JY Shi…

Index: Zhang, Yuan; Zhang, Yong; Sun, Ya Lei; Du, Xin; Shi, Jiao Yi; Wang, Wei; Wang, Wei David Chemistry - A European Journal, 2012 , vol. 18, # 20 p. 6328 - 6334

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Citation Number: 4

Abstract

Abstract We report herein for the first time the incorporation of a versatile organocatalyst, 4- (N, N-dimethylamino) pyridine (DMAP), into the network of a nanoporous conjugated polymer (NCP) by the “bottom-up” approach. The resulting DMAP-NCP material possesses highly concentrated and homogeneously distributed DMAP catalytic sites (2.02 mmol g− 1). DMAP-NCP also exhibits enhanced stability and permanent porosity due to the strong ...