Direct synthesis of organodichlorosilanes by the reaction of metallic silicon, hydrogen chloride and alkene/alkyne and by the reaction of metallic silicon and alkyl …

…, S Onodera, Y Yamamoto, E Suzuki, Y Ono

Index: Okamoto, Masaki; Onodera, Satoshi; Yamamoto, Yuji; Suzuki, Eiichi; Ono, Yoshio Journal of the Chemical Society, Dalton Transactions, 2001 , # 1 p. 71 - 78

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Abstract

Dichloroethylsilane was synthesized by the reaction of metallic silicon, hydrogen chloride and ethylene using copper (I) chloride as the catalyst, the silicon conversion and the selectivity for dichloroethylsilane being 36 and 47%, respectively. At a lower reaction ...