Dendritic metalloporphyrins with a distal H-bond donor as mimics of haemoglobin.
Beatrice Felber, Carlos Calle, Paul Seiler, Arthur Schweiger, François Diederich
Index: Org. Biomol. Chem. 1(7) , 1090-93, (2003)
Full Text: HTML
Abstract
We report the synthesis of iron(II) porphyrins functionalised with first- and second-generation dendrons as mimics of haemoglobin. The porphyrin core bears an ethynyl linker pointing towards the centre of the molecule, in an ideal position for the introduction of a series of distal ligands as potential H-bond donors by Pd0-catalysed Sonogashira cross-coupling.
Related Compounds
Related Articles:
2000-01-01
[Bioconjug. Chem. 11(6) , 868-75, (2000)]
2004-01-07
[Org. Biomol. Chem. 2(1) , 110-13, (2004)]
1-Methyl-1-vinyl-and 1-Methyl-1-(prop-2-enyl) silacyclobutane: Reagents for Palladium-Catalyzed Cross-Coupling Reactions of Aryl Halides. Denmark SE and Wang Z.
[Synthesis 2000(7) , 999-1003, (2000)]