Au(I)-catalyzed efficient synthesis of functionalized bicyclo[3.2.0]heptanes.
Guotao Li, Xiaogen Huang, Liming Zhang
Index: J. Am. Chem. Soc. 130(22) , 6944-5, (2008)
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Abstract
An efficient Au(I)-catalyzed synthesis of highly strained and functionalized bicyclo[3.2.0]heptanes is developed. Subsequent couplings with various nucleophiles offer additional structural features/complexity. These one-pot, three-component reactions are proposed to proceed via a key 1,3-dipolar cycloaddition between a Au carbenoid-containing carbonyl ylide and ethyl vinyl ether.
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