Synthesis of N??Alkoxy Amines via Catalytic Oxidation of Hydrocarbons
…, F Schwarzenbach, PA van der Schaaf…
Index: Kirner, Hans-J.; Schwarzenbach, Franz; Van Der Schaaf, Paul A.; Hafner, Andreas; Rast, Valerie; Frey, Markus; Nesvadba, Peter; Rist, Guenther Advanced Synthesis and Catalysis, 2004 , vol. 346, # 5 p. 554 - 560
Full Text: HTML
Citation Number: 12
Abstract
Abstract: Sterically hindered N-alkoxy amines 3 are synthesized in good yields by coupling nitroxides 2 with hydrocarbyl radicals generated in situ by t- BuOOH hydrogen abstraction from hydrocarbons. The reaction is catalyzed by copper halides as well as by onium iodides. ... Keywords: N-alkoxy amines; tert-butyl hydroperox- ide; copper; hydrocarbons; nitroxides; oxidation; phase-transfer catalysis; radical reactions; TEMPO
Related Articles:
Novel methodology for the synthesis of N-alkoxyamines
[Braslau, Rebecca; Tsimelzon, Anna; Gewandter, Jennifer Organic Letters, 2004 , vol. 6, # 13 p. 2233 - 2235]
[Takeuchi, Masayuki; Kano, Koji Bulletin of the Chemical Society of Japan, 1994 , vol. 67, # 6 p. 1726 - 1733]
[Journal of Organic Chemistry, , vol. 53, # 8 p. 1629 - 1632]