Dual radical/polar Pudovik reaction: application field of new activation methods
D Semenzin, G Etemad-Moghadam…
Index: Semenzin, Delphine; Etemad-Moghadam, Guita; Albouy, Dominique; Diallo, Ousmane; Koenig, Max Journal of Organic Chemistry, 1997 , vol. 62, # 8 p. 2414 - 2422
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Citation Number: 110
Abstract
The Pudovik reaction (addition of organophosphorus compounds containing a labile PH bond with alkenes and alkynes) can progess via a radical or (and) ionic mechanism. A comparative and systematic study including various reagents and different activation methods (heating, photochemical or ultrasonic irradiation, and dry medium supported reactions) is presented. Photolysis is the most efficient method for the radical processes, ...
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