Preparation of tertiary amines via the oxidative coupling of polyfunctional aryl and heteroaryl amidocuprates
M Kienle, SR Dubbaka, V del Amo, P Knochel
Index: Kienle, Marcel; Dubbaka, Srinivas Reddy; Del Amo, Vicente; Knochel, Paul Synthesis, 2007 , # 8 p. 1272 - 1278
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Citation Number: 29
Abstract
Abstract Highly functionalized tertiary amines can be prepared by the oxidative coupling of polyfunctional lithium amidocuprates using chloranil as an oxidant. A high functional group tolerance and insensibility to steric hindrance characterize this general amination reaction. Herein, we report a practical procedure for the preparation of aryl and heteroaryl tertiary amines.
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