Copper-catalyzed aerobic oxidative amination of arylboronic acid with aminal under base-free conditions
Y Zhou, Y Xie, L Yang, P Xie, H Huang
Index: Zhou, Yanping; Xie, Yinjun; Yang, Lei; Xie, Pan; Huang, Hanmin Tetrahedron Letters, 2013 , vol. 54, # 21 p. 2713 - 2716
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Citation Number: 13
Abstract
A new process involving copper-catalyzed oxidative amination reaction of various arylboronic acids with aminals under mild conditions has been developed. The key copper- amide species involved in the C–N bond-forming process was generated via C–N bond cleavage of aminal under base-free conditions. Moderate yields of desired amination products can be obtained under mild conditions when air was served as oxidant and ...
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