Use of thallium(I) ethoxide in Suzuki cross coupling reactions.
S A Frank, H Chen, R K Kunz, M J Schnaderbeck, W R Roush
Index: Org. Lett. 2(17) , 2691-4, (2000)
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Abstract
[reaction: see text]Thallium(I) ethoxide promotes Suzuki cross couplings for a range of vinyl- and arylboronic acids with vinyl and aryl halide partners in good to excellent yields. This reagent offers distinct advantages over thallium(I) hydroxide in terms of commercial availability, stability, and ease of use.
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