Journal of heterocyclic chemistry

A comparison of nucleophilic reactions of 3??benzenesulfonyloxyalloxazine and its 1??methyl analog

JM Hamby, L Bauer

Index: Hamby, James M.; Bauer, Ludwig Journal of Heterocyclic Chemistry, 1987 , vol. 24, p. 1013 - 1024

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Citation Number: 5

Abstract

Abstract Reactions of 3-benzenesulfonyloxyalloxazine (1a) and its 1-methyl analog 1b with a number of nucleophilic reagents are reported. Relatively small nucleophiles, such as hydroxide ion, methanol, ethanol, methylamine, hydrazine and hydroxylamine converted 1a to 4-carboxy-s-triazolo [4, 3-a] quinoxalin-1 (2H)-ones and the corresponding esters or amides. As the size of the amine increased from methylamine to ethylamine, ...

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