Use of Molecular Oxygen as a Reoxidant in the Synthesis of 2??Substituted Benzothiazoles via Palladium??Catalyzed C H Functionalization/Intramolecular C S Bond …

K Inamoto, C Hasegawa, J Kawasaki…

Index: Inamoto, Kiyofumi; Hasegawa, Chisa; Kawasaki, Junpei; Hiroya, Kou; Doi, Takayuki Advanced Synthesis and Catalysis, 2010 , vol. 352, # 14-15 p. 2643 - 2655

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Citation Number: 57

Abstract

Abstract Molecular oxygen (O 2) was successfully employed as a reoxidant in cyclizations of thiobenzanilides 1a–s through a palladium-catalyzed C [BOND] H functionalization/ intramolecular C [BOND] S bond formation process, leading to an efficient, green method for the synthesis of 2-arylbenzothiazoles 2a–s. Addition of cesium fluoride (CsF) greatly enhanced the reactions, which produced variously substituted 2-arylbenzothiazoles with ...

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