Photo-and Thermal-Induced Multistructural Transformation of 2-Phenylazolyl Chelate Boron Compounds

…, LD Chen, ML Brown, NJ Mosey, S Wang

Index: Rao, Ying-Li; Amarne, Hazem; Chen, Leanne D.; Brown, Matthew L.; Mosey, Nicholas J.; Wang, Suning Journal of the American Chemical Society, 2013 , vol. 135, # 9 p. 3407 - 3410

Full Text: HTML

Citation Number: 25

Abstract

The new N, C-chelate boron compounds B (2-phenylazolyl) Mes2 [Mes= mesityl; azolyl= benzothiazolyl (1a), 4-methylthiazolyl (2a), benzoxazolyl (3a), benzimidazolyl (4a)] undergo an unprecedented multistructural transformation upon light irradiation or heating, sequentially producing isomers b, c, d, and e. The dark isomers b generated by photoisomerization of a undergo a rare thermal intramolecular H-atom transfer (HAT), ...

Related Articles:

Tri-lacunary polyoxometalates of Na 8 H [PW 9 O 34] as heterogeneous Lewis base catalysts for Knoevenagel condensation, cyanosilylation and the synthesis of …

[Zhao, Shen; Chen, Yang; Song, Yu-Fei Applied Catalysis A: General, 2014 , vol. 475, p. 140 - 146]

2-(2-Arylphenyl) benzoxazole As a Novel anti-inflammatory scaffold: synthesis and biological evaluation

[Kumar, Dinesh; Rudrawar, Santosh; Chakraborti, Asit K. Australian Journal of Chemistry, 2008 , vol. 61, # 11 p. 881 - 887]

Copper-Mediated Synthesis of Substituted 2-Aryl-N-benzylbenzimidazoles and 2-Arylbenzoxazoles via C–H Functionalization/C–N/C–O Bond Formation

[Guru, Murali Mohan; Ali, Md Ashif; Punniyamurthy, Tharmalingam Journal of Organic Chemistry, 2011 , vol. 76, # 13 p. 5295 - 5308]

Copper-Mediated Synthesis of Substituted 2-Aryl-N-benzylbenzimidazoles and 2-Arylbenzoxazoles via C–H Functionalization/C–N/C–O Bond Formation

[Guru, Murali Mohan; Ali, Md Ashif; Punniyamurthy, Tharmalingam Journal of Organic Chemistry, 2011 , vol. 76, # 13 p. 5295 - 5308]

Copper-Mediated Synthesis of Substituted 2-Aryl-N-benzylbenzimidazoles and 2-Arylbenzoxazoles via C–H Functionalization/C–N/C–O Bond Formation

[Guru, Murali Mohan; Ali, Md Ashif; Punniyamurthy, Tharmalingam Journal of Organic Chemistry, 2011 , vol. 76, # 13 p. 5295 - 5308]

More Articles...