Coordination complexes derived from 3, 6-di (2-pyridyl)-1, 4-dihydro-1, 2, 4, 5-tetrazine (DPDHT). Synthesis and molecular structure of [(DPT)(GaMe2) 2]
PN Preston, SJ Rettig, A Storr…
Index: Preston, Peter N.; Rettig, Steven J.; Storr, Alan; Trotter, James Canadian Journal of Chemistry, 1998 , vol. 76, # 12 p. 1800 - 1804
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Citation Number: 3
Abstract
The facile reaction of 3, 6-di (2-pyridyl)-1, 4-dihydro-1, 2, 4, 5-tetrazine (DPDHT)(1) with trimethylgallium has resulted in the formation of the purple crystalline product,[(DPT)(GaMe2 ) 2](2), via methane elimination. Crystals of [(DPT)(GaMe2) 2] are orthorhombic, Pbca, a= 15.380 (2), b= 21.642 (4), c= 11.355 (2) Å, Z= 8. The structure was solved by heavy-atom Patterson methods and refined by full-matrix least-squares procedures to R= 0.035 for ...
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