Aryl (dimethyl) gallium compounds and methyl (diphenyl) gallium: Synthesis, structure, and redistribution reactions
…, J Izundu, B Neumann, A Mix, HG Stammler
Index: Jutzi, Peter; Izundu, Joseph; Neumann, Beate; Mix, Andreas; Stammler, Hans-Georg Organometallics, 2008 , vol. 27, # 18 p. 4565 - 4571
Full Text: HTML
Citation Number: 7
Abstract
The synthesis of dimethyl (phenyl) gallium (1), dimethyl (4-methylphenyl) gallium (2), dimethyl (4-tert-butylphenyl) gallium (3), and methyl (diphenyl) gallium (4) is described. X- ray crystallographic studies revealed the presence of trigonal planar coordinate gallium atoms in monomeric molecules, which associate to polymeric strands by intermolecular gallium π-aryl contacts. Redistribution reactions take place at higher temperatures and at ...
Related Articles:
Selectivity and reactivity in reactions of methylaryltitanium (IV) complexes with electrophiles
[Organometallics, , vol. 2, p. 1400 - 1405]
Electrophilic cleavages in (CH3) 3SnCH2M (CH3) 3 (M= Sn, Ge, Si, C). 1. Product distribution
[Organometallics, , vol. 4, p. 821 - 825]
[Organometallics, , vol. 27, # 18 p. 4565 - 4571]