Organic Letters 2003-12-25

Direct carbamoylation of alkenyl halides.

Robert F Cunico, Bikash C Maity

Index: Org. Lett. 5 , 4947, (2003)

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Abstract

Alkenyl chlorides and bromides are converted into tertiary enamides by treatment with a carbamoylsilane in toluene at 110 degrees C in the presence of phosphine-palladium(0) catalysts. [reaction: see text]

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