Catalytic enantioselective hetero-Diels-Alder reactions of an azo compound.
Masanori Kawasaki, Hisashi Yamamoto
Index: J. Am. Chem. Soc. 128 , 16482, (2006)
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Abstract
This communication describes studies in which an azo hetero-Diels-Alder adduct was furnished in high regio- and enantioselectivity using azopyridine as a reagent and silver as a catalyst. The obtained hetero-Diels-Alder adduct was easily converted to the corresponding chiral 1,4-diamino alcohol.
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