Acyl iodides in organic synthesis. Reactions with morpholine, piperidine, and N-hydrocarbylpiperidines
MG Voronkov, IP Tsyrendorzhieva…
Index: Voronkov; Tsyrendorzhieva; Rakhlin Russian Journal of Organic Chemistry, 2010 , vol. 46, # 6 p. 794 - 797
Full Text: HTML
Citation Number: 7
Abstract
Abstract Acyl iodides RCOI (R= Me, Ph) reacted with morpholine and piperidine to give the corresponding N-acyl derivatives and morpholine or piperidine hydroiodides. Reactions of acyl iodides with N-methyl-and N-ethylpiperidines involved cleavage of the exocyclic RN bond with formation of N-acylpiperidine and alkyl iodide and were accompanied (to insignificant extent) by cleavage of the endocyclic NC bond, leading to N-alkyl-N-(5- ...
Related Articles:
[Mei, Hui; Hu, Jianglin; Xiao, Se; Lei, Yizhu; Li, Guangxing Applied Catalysis A: General, 2014 , vol. 475, p. 40 - 47]
Solvent free, N, N′-carbonyldiimidazole (CDI) mediated amidation
[Verma, Sanjeev K.; Ghorpade, Ramarao; Pratap, Ajay; Kaushik Tetrahedron Letters, 2012 , vol. 53, # 19 p. 2373 - 2376]
Electrochemical synthesis of amides: direct transformation of methyl ketones with formamides
[Huang, Haolai; Yuan, Gaoqing; Li, Xianwei; Jiang, Huanfeng Tetrahedron Letters, 2013 , vol. 54, # 52 p. 7156 - 7159]
Double carbonylation of aryl iodides with diethylamine catalyzed by dinuclear palladium complexes
[Journal of Organometallic Chemistry, , vol. 687, # 2 p. 436 - 443]
Preparation of amides mediated by isopropylmagnesium chloride under continuous flow conditions
[Munoz, Juan De M.; Alcazar, Jesus; De La Hoz, Antonio; Diaz-Ortiz, Angel; Alonso De Diego, Sergio-A. Green Chemistry, 2012 , vol. 14, # 5 p. 1335 - 1341]