The Reaction of α, α-Dichlorobenzyltrimethylsilane with Aldehydes and Ketones
GL Larson, JA Prieto, L Valle
Index: Larson, Gerald L.; Prieto, Jose A.; Valle, Luis del Synthetic Communications, 1989 , vol. 19, # 7,8 p. 1405 - 1412
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Citation Number: 6
Abstract
Abstract The reaction of α, α-dichlorobenzyltrimethylsilane with carbonyl compounds in the presence of fluoride ion fails to give reasonable yields of the α, α-dichlorobenzyl adducts except when carried out in the presence of zinc iodide and in HMPA as solvent. Under these conditions moderate yields of the adducts can be obtained with cyclohexanone, cyclohexenone, benzaldhyde and trans cinnamaldehyde. These reactions were ...
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