Rates and Mechanism for the Solvolyses of 2, 2-Dimethyl-2-sila-1-indanyl Bromide and α-Trialkylsilylbenzyl p-Toluenesulfonates. α-Silicon Effect on the Stability of …
N Shimizu, E Osajima, Y Tsuno
Index: Shimizu, Nobujiro; Osajima, Erika; Tsuno, Yuho Bulletin of the Chemical Society of Japan, 1991 , vol. 64, # 4 p. 1145 - 1152
Full Text: HTML
Citation Number: 20
Abstract
α-Silicon effect on the benzylic solvolysis has been investigated. The solvolysis of 2, 2- dimethyl-2-sila-1-indanyl bromide in aq acetone exhibits a linear response to the solvent ionizing power Y Br with a slope m close to unity (m= 0.93) and gives the corresponding alcohol without skeletal rearrangement indicative of akc mechanism; it solvolyzes 4.98× 10 2 times less rapidly than a carbon reference, 2, 2-dimethyl-1-indanyl bromide, in 60% aq ...
Related Articles:
Intramolecular Palladium-Catalyzed Alkane C− H Arylation from Aryl Chlorides
[Rousseaux, Sophie; Davi, Michael; Sofack-Kreutzer, Julien; Pierre, Cathleen; Kefalidis, Christos E.; Clot, Eric; Fagnou, Keith; Baudoin, Olivier Journal of the American Chemical Society, 2010 , vol. 132, # 31 p. 10706 - 10716]
Intramolecular Palladium-Catalyzed Alkane C− H Arylation from Aryl Chlorides
[Rousseaux, Sophie; Davi, Michael; Sofack-Kreutzer, Julien; Pierre, Cathleen; Kefalidis, Christos E.; Clot, Eric; Fagnou, Keith; Baudoin, Olivier Journal of the American Chemical Society, 2010 , vol. 132, # 31 p. 10706 - 10716]
[Warrick,P.; Saunders,W.H. Journal of the American Chemical Society, 1962 , vol. 84, p. 4095 - 4100]
[Bruson,H.A.; Plant,H.L. Journal of Organic Chemistry, 1967 , vol. 32, p. 3356 - 3362]
[Bruson,H.A.; Plant,H.L. Journal of Organic Chemistry, 1967 , vol. 32, p. 3356 - 3362]