Catalysis Communications

Efficient oxidative coupling of amines to imines catalyzed by manganese (III) meso-tetraphenylporphyrin chloride under ambient conditions

QL Yuan, XT Zhou, HB Ji

Index: Yuan, Qiu-Lan; Zhou, Xian-Tai; Ji, Hong-Bing Catalysis Communications, 2010 , vol. 12, # 3 p. 202 - 206

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Citation Number: 25

Abstract

Highly efficient oxidative coupling of amines to imines by tert-butyl hydroperoxide (t-BuOOH) in the presence of metalloporphyrins has been reported. Manganese porphyrin showed excellent activity and selectivity for the oxidative coupling of amines to imines under ambient conditions. Moreover, a plausible mechanism involving high valence oxo intermediate has been proposed.

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