Hydrosilylation Catalyzed with Rh (PPh3) 3Cl/Ionic-Liquid–Functionalized SiO2
J Li, J Peng, Y Bai, Y Hu, H Qiu, G Lai…
Index: Li, Jiayun; Peng, Jiajian; Bai, Ying; Hu, Yingqian; Qiu, Huayu; Lai, Guoqiao; Li, Xiaonian Phosphorus, Sulfur and Silicon and the Related Elements, 2010 , vol. 185, # 2 p. 484 - 490
Full Text: HTML
Citation Number: 5
Abstract
Ionic liquid–modified silica has been prepared by a “one-pot” reaction of activated silica, 3- chloropropyltriethoxysilane, and alkylimidazole or pyridine. It was found that the catalytic activity and β-adduct selectivity of the supported catalyst Rh (PPh3) 3Cl/ionic-liquid– modified-SiO2 for the hydrosilylation reaction of alkenes with triethoxysilane was significantly improved. Furthermore, the catalyst system could be recovered easily.
Related Articles:
[Li, Ji; Yang, Chunhui; Zhang, Lei; Ma, Tianlong Journal of Organometallic Chemistry, 2011 , vol. 696, # 9 p. 1845 - 1849]
Phosphinite-Iminopyridine Iron Catalysts for Chemoselective Alkene Hydrosilylation
[Peng, Dongjie; Zhang, Yanlu; Du, Xiaoyong; Zhang, Lei; Leng, Xuebing; Walter, Marc D.; Huang, Zheng Journal of the American Chemical Society, 2013 , vol. 135, # 51 p. 19154 - 19166]
Phosphinite-Iminopyridine Iron Catalysts for Chemoselective Alkene Hydrosilylation
[Peng, Dongjie; Zhang, Yanlu; Du, Xiaoyong; Zhang, Lei; Leng, Xuebing; Walter, Marc D.; Huang, Zheng Journal of the American Chemical Society, 2013 , vol. 135, # 51 p. 19154 - 19166]
Preparation and Properties of Trialkylfluorosilanes1
[Szmant,H.H. et al. Journal of Organic Chemistry, 1962 , vol. 27, p. 261 - 265]
[Hilal, Hikmat S.; Khalaf, Shukri; Jondi, Waheed Journal of Organometallic Chemistry, 1993 , vol. 452, # 1.2 p. 167 - 173]