Synthesis and characterization of bis (trifluoromethyl) thiophosphoryl-. mu.-thio-bis (trifluoromethyl) phosphine and di (bis (trifluoromethyl) thiophosphoryl) disulfide

RG Cavell, AA Pinkerton

Index: Pinkerton,A.A.; Cavell,R.G. Journal of the American Chemical Society, 1971 , vol. 93, p. 2384 - 2390

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Citation Number: 2

Abstract

Conclusions As expected for recoil chemistry, a wide variety of products has been observed in this work. A median excitation energy for the unimolecular decompositions of cyclohexene- t has been determined to be 5 eV for the gas-phase studies. The liquid-phase studies gave a median excitation energy of 8 eV. These calculations are based on the premise that the formation of ethene-t and 1, 3-butadiene-t results primarily from the unimolecular ...

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