Simple and efficient palladium-catalyzed carbonylation of iodoxyarenes in water under mild conditions
VV Grushin, H Alper
Index: Grushin, Vladimir V.; Alper, Hovard Journal of Organic Chemistry, 1993 , vol. 58, # 18 p. 4794 - 4795
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Citation Number: 16
Abstract
Summary: Iodoxyarenes (ArI02) readily react with CO (1 atm) in water, in the presence of Naz [PdC&l (0.1%) and Na2C03 at 40-50" C, to give the corresponding carboxylic acids, ArCOOH, in 5589% isolated yield. Particularly attractive features of the reaction are that,
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