Novel System for Decarboxylative Bromination of. ALPHA.,. BETA.-Unsaturated Carboxylic Acids with Diacetoxyiodobenzene

…, BD Shewale, SB Kosalge, PK Deshmukh…

Index: Fursule, Ravindra Abhykumar; Patil, Pravin Onkar; Shewale, Bharti Devaji; Kosalge, Satish Bhaskar; Deshmukh, Prashant Krishnarao; Patil, Dilip Ashok Chemical and Pharmaceutical Bulletin, 2009 , vol. 57, # 11 p. 1243 - 1245

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Citation Number: 14

Abstract

A simple and mild method for the conversion of varieties of α, β-unsaturated carboxylic acids to the corresponding bromoalkenes using diacetoxyiodobenzene (IBD) in combination with tetraethyl-ammonium bromide (TEAB) at room temperature is discussed. Advantages of this system are short reaction time, easy work up and gave good to excellent yields.

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