Unexpected chemoselective debromination and reduction of 1, 1-dibromo-1-alkenes mediated by samarium metal in methanol
L Wang, P Li, Y Xie, Y Ding
Index: Wang, Lei; Li, Pinhua; Xie, Yuanyuan; Ding, Yanbin Synlett, 2003 , # 8 p. 1137 - 1140
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Citation Number: 6
Abstract
Abstract An unexpected samarium metal mediated chemoselective debromination and reduction of 1, 1-dibromo-1-alkenes in methanol has been developed, which generates vinyl monobromides, alkenes, and alkanes respectively with appropriate molar ratio of samarium to 1, 1-dibromo-1-alkene.
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