Chemistry of diphenyltetrafluorophosphazene: Reactions with dilithiated diols

…, K Muralidharan, MS Kumar, P Venugopalan

Index: Elias, Anil J.; Muralidharan; Senthil Kumar; Venugopalan Journal of Fluorine Chemistry, 2006 , vol. 127, # 8 p. 1046 - 1053

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Citation Number: 4

Abstract

Reaction of gem-diphenyltetrafluorophosphazene,[1, 1-(C6H5) 2] P3N3F4 (1) with LiO (CH2) 3OLi resulted in the formation of four products, spiro-{3, 3-[O (CH2) 3O]}[1, 1-(C6H5) 2] P3N3F2 (2), ansa-{3, 5-[O (CH2) 3O]}[1, 1-(C6H5) 2P3N3F2](3), bridged-[1, 1-(C6H5) 2N3P3F3][O (CH2) 3O][1, 1-(C6H5) 2N3P3F3](4) and dangling-[HO (CH2) 3O][1, 1-(C6H5) 2P3N3F3](5) derivatives of 1, among which compound 5 was found to be the major ...