Stereoselective synthesis of the polyketide chain of nagahamide A
DK Mohapatra, SR Chaudhuri, G Sahoo…
Index: Mohapatra, Debendra K.; Chaudhuri, Siddhartha Ray; Sahoo, Gokarneswar; Gurjar, Mukund K. Tetrahedron Asymmetry, 2006 , vol. 17, # 18 p. 2609 - 2616
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Citation Number: 12
Abstract
A carbohydrate based approach for the enantioselective synthesis of the polyketide acid unit present in nagahamide A has been reported. Reductive ring opening of a chiral cyclopropane ketone group to enantioselectively install the methyl and propyl groups, is a salient feature of this synthesis.
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