Neopentylallithium: IV. Reactions in ether solvents
WH Glaze, DJ Berry, DP Duncan
Index: Glaze,W.H. et al. Journal of Organometallic Chemistry, 1973 , vol. 52, p. 233 - 240
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Citation Number: 11
Abstract
Abstract Protolysis and ketone addition reactions are reported for neophentylallyllithium in THF solvent. The yield of the trans-C 8 H 16 olefin essentially constant for protolysis with the following active hydrogen compounds: water, tert-butanol, 1-hexyne, cyclopentadiene, fluorene, and triphenylmethane. The relative yields of the cis-and α-neopentallyl isomers apparently depend on the steric bulk as well as the strength of the acid. The degree of ...
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