1, 2-Disubstituierte ferrocene via 2-ferrocenyl-2-oxazoline
G Schmitt, P Klein, W Ebertz
Index: Schmitt, Guenter; Klein, Peter; Ebertz, Wolfgang Journal of Organometallic Chemistry, 1982 , vol. 234, # 1 p. 63 - 72
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Abstract
Abstract 2-Ferrocenyl-2-oxazolines, available from the reaction of chlorocarbonylferrocene with aziridines and subsequent acid-catalyzed isomerisation, are metallated (lithiated) regiospecifically in the 2-position of the ferrocenyl moiety. Further reaction of the metallated compounds with electrophiles gives 1, 2-disubstituted ferrocenes solely. In contrast to the analogous 2-phenyl-2-oxazolines, 2-ferrocenyl-2-oxazolines exhibit high stability under ...
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