Organo-silicon Compounds. III. 1 α-and β-Chloroalkyl Silanes and the Unusual Reactivity of the Latter2

LH Sommer, FC Whitmore

Index: Sommer; Whitmore Journal of the American Chemical Society, 1946 , vol. 68, p. 486

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Citation Number: 78

Abstract

In 1939 Kharasch reported sulfuryl chloride activated by benzoyl peroxide as a good chlorinating agent for aliphatic hydrocarbons and many of their derivative^.^ The application of this method to organo-silicon compounds gives excellent yields of monochlorinated products. It is much more convenient than photochemical chlorination.