Essais de Chloration Dirigée XVIII. Photochloration Comparée D'Alkyltrichlorosilanes et de Trichloro??1, 1, 1 Alcanes [1] 1. Résultats en Présence de Deux Solvants ( …

T Burton, A Bruylants

Index: Burton,T.; Bruylants,A. Bulletin des Societes Chimiques Belges, 1972 , vol. 81, p. 639 - 642

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Abstract

A series of alkyltrichlorosilanes, R-SiCI,(with R= C2H5-, n. C, H,-, i. C3H7-, C, H, and an other one of trichloro-alkanes, R '-CCI,(with R'= C, H,-, C, H,-, C, Hg-, C, H, 3-) were submitted to photochlorination, in two different solvents (CCI,, CS,). For each parent compound, experimental distribution (RE) of monochlorinated isomers are qualitatively discussed; activation or deactivation of hydrogen atoms, by the neighbouring substituents ...