Rearrangements and conformations of chloroalkyl radicals by electron spin resonance

KS Chen, DYH Tang, LK Montgomery…

Index: Chen,K.S. et al. Journal of the American Chemical Society, 1974 , vol. 96, p. 2201 - 2208

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Citation Number: 33

Abstract

Abstract: A variety of alkyl radicals containing one or more chlorine atoms substituted in the cy, p, and y positions are generated for esr study. The migration of chlorine from the/3 to cy position occurs readily if the centers are tertiary and primary, respectively, but no rearrangements are observed from more remote positions regardless of the pattern of substitution. The configuration at the radical center of a, a-dichloroalkyl radicals is ...