Temperature-sensitive aliphatic polyesters: synthesis and characterization of γ-substituted caprolactone monomers and polymers
J Hao, J Servello, P Sista, MC Biewer…
Index: Hao, Jing; Servello, John; Sista, Prakash; Biewer, Michael C.; Stefan, Mihaela C. Journal of Materials Chemistry, 2011 , vol. 21, # 29 p. 10623 - 10628
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Citation Number: 22
Abstract
Synthesis and ring-opening polymerization of γ-substituted ε-caprolactone monomers containing octyloxy and 2-[2-(2-methoxyethoxy) ethoxy] ethoxy functional groups is reported. An amphiphilic block copolymer containing hydrophobic poly (γ-octyloxy-ε-caprolactone) and hydrophilic poly {γ-2-[2-(2-methoxyethoxy) ethoxy] ethoxy-ε-caprolactone} forms micelles in aqueous solution above the critical micellar concentration of 1.74× 10− 3 g L− ...
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