Tetrahedron Letters

The coordination chemistry and reactivity of amino-dithiaphospholanes with rhodium, iridium, and ruthenium

S Costin, SL Sedinkin, EB Bauer

Index: Costin, Stephen; Sedinkin, Sergey L.; Bauer, Eike B. Tetrahedron Letters, 2009 , vol. 50, # 8 p. 922 - 925

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Citation Number: 7

Abstract

Novel amino-dithiaphospholane complexes of ruthenium, iridium, and rhodium were synthesized, and their properties were studied. Reaction of the new amino- dithiaphospholane (RS) 2PNR2′(R= binaphthyl, R′= CH2Ph,(rac)-4) with [RuCl2 (p- cymene)] 2 afforded [RuCl2 (p-cymene)((rac)-4)] in 67% isolated yield. Similarly, the new amino-dithiaphospholanes (RS) 2PNR2′(R= cyclohexyl,(rac)-7) and (RS) 2PNR2′(R= ...