The Journal of Organic Chemistry

Evaluation of lithium amide base formation at low temperature via carbon-13 NMR spectroscopy

KF Podraza, RL Bassfield

Index: Podraza, Kenneth F.; Bassfield, Ronald L. Journal of Organic Chemistry, 1988 , vol. 53, # 11 p. 2643 - 2644

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Citation Number: 20

Abstract

0022-3263/88/1953-2643 $01.50/0 tetramethylpiperidide (LTMP) to name a few. The usefulness of lithium amide bases in carbanion formation is well established., As a result of their popularity, the preparation of each respective base has been accomplished by a wide variety of experimental conditions. For instance, LDA has been prepared by the addition of n- butyllithium in hexane to a solution of diisopropylamine in tetrahydrofuran (THF) at 0" C ...

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