… hindered lithium amides and their diethyl etherates: crystal and molecular structures of [Li {N (SiMe3) 2}(OEt2)] 2 and tetrakis (2, 2, 6, 6-tetramethylpiperidinatolithium)

MF Lappert, MJ Slade, A Singh, JL Atwood…

Index: Lappert, Michael F.; Slade, Martin J.; Singh, Anirudh; Atwood, Jerry L.; Rogers, Robin D.; Shakir, Riz Journal of the American Chemical Society, 1983 , vol. 105, # 2 p. 302 - 304

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Citation Number: 194

Abstract

Figure 1. Molecular structure of (Li [N (SiMe,),](OEtz)) z, 1, with the atoms represented by their 50% probability ellipsoids for thermal motion. The dimer resides about a crystallographic 222 site: one 2-fold axis contains the lithium and oxygen atoms, one the nitrogen atoms, and the third is perpendicular to the LizNz plane.