The Journal of Organic Chemistry

Iodide catalysis of oxidations with dimethyl sulfoxide. Convenient two-step synthesis of. alpha. diketones from. alpha.-methylene ketones

DP Bauer, RS Macomber

Index: Bauer,D.P.; Macomber,R.S. Journal of Organic Chemistry, 1975 , vol. 40, p. 1990 - 1992

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Citation Number: 68

Abstract

Receiued January 24, 1975 a diketones are not only interesting with regard to conformational analysis, l electronic spectroscopy, 2 and photochemi~ try,~ but also because they are versatile synthetic intermediates and they undergo a variety of unique reactions, including the bend-benzilic acid rearrangement4 and dioxaphospholene f~ rmation.~ In connection with our synthesis of macrotricyclic hydrocarbons, we needed ...

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